An investigation of the gas-phase reactions of molecular oxygen with the molecular anions of 17 compounds formed by resonance electron capture was undertaken using a pulsed e-beam high-pressure mass spectrometer. The molecular anions of sulphur hexafluoride, perfluromethylcyclohexane, cis-and trans-
Reaction of molecular oxygen with paramagnetic organometallic cluster anions
✍ Scribed by André Darchen; Christian Mahé; Henri Patin
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 259 KB
- Volume
- 251
- Category
- Article
- ISSN
- 0022-328X
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Rate constants at room temperature for the reactions of oxygen with Sn~ (n= 1-9) and Pb~-(n= 1-7) cluster anions are reported from flow-tube reactor kinetics measurements. A large variation in reactivity for different cluster sizes is observed, with reaction efficiencies ranging from 2% to 30% of th
## Abstract The anion radical of acetylacetonate is formed by the reaction of nickel (II) acetylacetonate with Grignard reagents. From the two coupling constants found in the e.s.r. spectrum, the one of 2·6 G was assigned to the methine proton and the one of 12·5 G to the six equivalent methyl prot