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Organometallic Intermediates Formed in the Reaction of Ethers with Potassium Anions

✍ Scribed by Andrzej Stolarzewicz; Zbigniew Grobelny; Adalbert Maercker

Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract In the reactions of alkyl‐substituted‐benzenecarboxylic and ‐2‐hydroxybenzenecarboxylic acids (ArCOOH) with alkyl‐substituted phenyl Grignard reagents (RMgX) in the presence of nickel, ketyl radicals ArCO^−^R are formed. The __para__ substituents (H, Me, Et, Isopr and __t__‐Bu) of R i