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Interactions of Au cluster anions with oxygen

✍ Scribed by Sun, Qiang; Jena, Puru; Kim, Young Dok; Fischer, Matthias; Ganteför, Gerd


Book ID
121502975
Publisher
American Institute of Physics
Year
2004
Tongue
English
Weight
675 KB
Volume
120
Category
Article
ISSN
0021-9606

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Rate constants at room temperature for the reactions of oxygen with Sn~ (n= 1-9) and Pb~-(n= 1-7) cluster anions are reported from flow-tube reactor kinetics measurements. A large variation in reactivity for different cluster sizes is observed, with reaction efficiencies ranging from 2% to 30% of th