Reactions of Cobalt Cluster Anions with Oxygen, Nitrogen, and Carbon Monoxide
โ Scribed by Kapiloff, Elizabeth; Ervin, Kent M.
- Book ID
- 127092651
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 225 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Rate constants at room temperature for the reactions of oxygen with Sn~ (n= 1-9) and Pb~-(n= 1-7) cluster anions are reported from flow-tube reactor kinetics measurements. A large variation in reactivity for different cluster sizes is observed, with reaction efficiencies ranging from 2% to 30% of th
The reaction between ozone and carbon monoxide was reinvestigated in the range of 80-160ยฐC. The previously reported rate law -d[O,l/dt = k.[o,][Co] + k,[0,l2 was confirmed and simulated using a mechanism based on an impurity-initiated chain reaction. When the CO was sufficiently purified, k, tended