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Reaction of aluminum clusters, Aln (n=7−24), with oxygen and ammonia

✍ Scribed by Kiyokazu Fuke; Shinji Nonose; Noriyoshi Kikuchi; Koji Kaya

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 459 KB
Volume: 147
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)85012-7

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✦ Synopsis

The reaction of aluminum clusters, Al, (n = 7-24), formed by laser vaporization, with oxygen and ammonia was studied by using a fast flow reactor. It was found that the oxygen reacts strongly with aluminum clusters to form chemisorbed products while ammonia is adsorbed weakly with Al, in a physisorbcd form. In the reaction with oxygen under multiple collision conditions, a mixed cluster, A&,0,, was found to be formed selectively.

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