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The reactions of C2F5 radicals with benzene in the vapor phase

✍ Scribed by G. A. Chamberlain; E. Whittle

Publisher: John Wiley and Sons
Year: 1972
Tongue: English
Weight: 355 KB
Volume: 4
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550040107

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✦ Synopsis

C2F5 radicals were generated in the presence of benzene vapor by the reaction (C2FsCO)20 + hv -+ CO + C02 + 2CzFs

The radicals react with the benzene by addition and pseudo H abstraction

The rate constant k a d d for the addition reaction ( 7) is given by

where e = 2.303RT cal/mole and k , is the rate constant for combination of C2F5 radicals. The addition becomes reversible above 110°C. The reactions of CF3 and CzF5 radicals with benzene vapor are compared.

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