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Gas phase reactions of CF3, C2F5, and n-C3F7 with carbon tetrachloride

✍ Scribed by C. M. de Vöhringer; E. H. Staricco

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
245 KB
Volume
16
Category
Article
ISSN
0538-8066

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✦ Synopsis

The reactions of some perfluoroalkyl radicals with carbon tetrachloride have been studied using the photolysis of the corresponding perfluoroalkyl iodide as the free radical source. The Arrhenius parameters, based on the value of 2.3 x 1013 cm3 mol-' s-' for the self-combination rate constant of all radicals are: Reaction log(A/cm3 mol ' s-') E/kcal mol ~ ' CF3 + CCl, 12.8 11.3 C,F, + CCl, 12.8 11.6 n -C,F, + CC1,

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