Trimethylamine-bis(trifluoromethyl) boranes R(CF 3 ) 2 B ´NMe 3 (R = cis/trans-CF 3 CF=CF (1/2), HCºC (3), H 2 C=CH (4), C 2 H 5 (5), C 6 H 5 CH 2 (6), C 6 F 5 (7), C 6 H 5 (8)) react with NEt 3 ´3 HF depending on the nature of R at 155±200 °C under replacement of the trimethylamine ligand to form
✦ LIBER ✦
Reactivity of B(C6F5)3 with Oxovanadium(V) Complexes VOL3 (L = OCH2CF3, NEt2): Formation of the Organometallic Vanadium(V) Complex [VO(μ-OCH2CF3)(OCH2CF3)(C6F5)]2 and the Lewis Acid Adduct [(Et2N)3VO·B(C6F5)3]
✍ Scribed by Fabien Wolff; Robert Choukroun; Christian Lorber; Bruno Donnadieu
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 143 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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