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Reactivity of B(C6F5)3 with Oxovanadium(V) Complexes VOL3 (L = OCH2CF3, NEt2): Formation of the Organometallic Vanadium(V) Complex [VO(μ-OCH2CF3)(OCH2CF3)(C6F5)]2 and the Lewis Acid Adduct [(Et2N)3VO·B(C6F5)3]

✍ Scribed by Fabien Wolff; Robert Choukroun; Christian Lorber; Bruno Donnadieu


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
143 KB
Volume
2003
Category
Article
ISSN
1434-1948

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## Abstract Reaction of the side‐on end‐on dinitrogen complex [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐N~2~)] (1; in which NPN=(PhNSiMe~2~CH~2~)~2~PPh), with the Lewis acids XR~3~ results in the adducts [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐NNXR~3~)], XR~3~=GaMe~3~ (2), AlMe~3~ (3), and B(C~6~F~5~)~3~ (4). Th