The Synthesis, Structure and Reactivity of B(C6F5)3-Stabilised Amide (MNH2) Complexes of the Group 4 Metals
✍ Scribed by Andrew J. Mountford; William Clegg; Simon J. Coles; Ross W. Harrington; Peter N. Horton; Simon M. Humphrey; Michael B. Hursthouse; Joseph A. Wright; Simon J. Lancaster
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 322 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Ph~3~SnN(SiMe~3~)~2~ (1) was prepared in good yields by reaction of [{NaN(SiMe~3~)~2~}~2~·THF] (2) with Ph~3~SnF. Treatment of 1 with [H(OEt~2~)~2~][H~2~N{B(C~6~F~5~)~3~}~2~] (4) in dichloromethane afforded the stannylium cation [Ph~3~Sn(OEt~2~)][H~2~N{B(C~6~F~5~)~3~}~2~] (5), which was
The compound cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] has been used as the between [(C 6 F 5 ) 2 Ni(&µ-X) 2 Ni-(C 6 F 5 ) 2 ] 2-and L. The treatment of cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] with [M(SAr) 2 (dppe)] leads to the starting material for the preparation of the bimetallic complexes ethane], and the Pt). Th