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Cationic Alkyl Complexes of the Rare-Earth Metals: Synthesis, Structure, and Reactivity

✍ Scribed by Stefan Arndt; Jun Okuda


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
242 KB
Volume
347
Category
Article
ISSN
1615-4150

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Synthesis and Structural Characterizatio
✍ Hans W. GΓΆrlitzer; Michael Spiegler; Reiner Anwander πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 316 KB πŸ‘ 2 views

The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual Β΅ 2 ,Ξ· 4 :Ξ· 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc