Synthesis and Structural Characterizatio
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Hans W. GΓΆrlitzer; Michael Spiegler; Reiner Anwander
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Article
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1998
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John Wiley and Sons
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English
β 316 KB
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The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual Β΅ 2 ,Ξ· 4 :Ξ· 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc