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Synthesis, Structure, and Reactivity of Metal Complexes with Alkoxysilylmethyl Ligands

โœ Scribed by Markus Enders; Jochen Fink; Veronique Maillant; Hans Pritzkow


Publisher
John Wiley and Sons
Year
2001
Tongue
German
Weight
187 KB
Volume
627
Category
Article
ISSN
0372-7874

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Treatment of Ti(NtBu)Cl 2 (py) 2 (1, py = pyridine) with bulky stitution products [PhC(NiPr) 2 ] 2 Ti(NtBu)(py) (6) and [Ph 2 P(NSiMe 3 ) 2 ] 2 Ti(NtBu) (7). The bis(pyridine) adduct heteroallylic ligands in a 1:1 molar ratio affords the monosubstituted derivatives [PhC(NSiMe 3 ) 2 ]Ti(NtBu)Cl(py) 2