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Thiolate Chemistry of the Iron Group Elements: Synthesis and Structure of the Complexes [Co2{o-(SCH2)2C6H4}3]2⊖ and [Ni3{o-(SCH2)2C6H4}4]2⊖

✍ Scribed by Dr. Wolfgang Tremel; Prof. Dr. Bernt Krebs; Dr. Gerald Henkel


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
251 KB
Volume
23
Category
Article
ISSN
0044-8249

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Coordination Chemistry of [Nb2(S2)2]4+ C
✍ M. Sokolov; A. Virovets; W. Clegg 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 151 KB 👁 1 views

Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space