Synthesis of Homo- and Hetero-Bimetallic Complexes Containing the Ni(C6F5)2 Moiety – Crystal Structure of [(C6F5)2Ni(μ-SPh)2Pd(dppe)]

✍ Scribed by Gregorio Sánchez; Francisca Momblona; Mateo Sánchez; José Pérez; Gregorio López; Jaume Casabó; Elies Molins; Carles Miravitlles

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 333 KB
• Volume: 1998
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/(sici)1099-0682(199808)1998:8<1199::aid-ejic1199>3.0.co;2-k

✦ Synopsis

The compound cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] has been used as the between [(C 6 F 5 ) 2 Ni(&µ-X) 2 Ni-(C 6 F 5 ) 2 ] 2-and L. The treatment of cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] with [M(SAr) 2 (dppe)] leads to the starting material for the preparation of the bimetallic complexes

ethane], and the Pt). The X-ray diffraction study of [(C 6 F 5 ) 2 Ni(µ-SPh) 2 Pd(dppe)] shows that both metal atoms, Ni and Pd, are trimetallic[(C 6 F 5 ) 2 Ni(µ-NCS) 2 Pd(µ-SCN) 2 Ni(C 6 F 5 ) 2 ] 2-. The mononuclear compounds [(C 6 F 5 ) 2 NiLX] (L = PPh 3 , coordinated in a slightly distorted square-planar geometry and the µ-thiolato groups are in the syn conformation. P(C 6 H 4 MeO-p) 3 ; X = SCN, OCN) are obtained by reaction