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New Di- and Trinuclear Complexes with Pyrazolato Bridges. Crystal Structures of [{(C6F5)2Pd(μ-pz)(μ-Cl)}2Pd]2– and [(C6F5)2Pd(μ-pz)2Pd(η3-C4H7)] (pz = pyrazolate)

✍ Scribed by José Ruiz; Félix Florenciano; Miguel A. Sánchez; Gregorio López; M. Carmen Ramírez de Arellano; José Pérez


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
386 KB
Volume
2000
Category
Article
ISSN
1434-1948

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✦ Synopsis


New Di-and Trinuclear Complexes with Pyrazolato Bridges. Crystal Structures of [{(C 6 F 5 ) 2 Pd(µ-pz)(µ-Cl)} 2 Pd] 2-and [(C 6 F 5 ) 2 Pd(µ-pz) 2 Pd(η 3 -C 4 H 7 )] (pz ‫؍‬ pyrazolate)

Jose ´Ruiz,* [a] Fe ´lix Florenciano, [a]


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Synthesis of Homo- and Hetero-Bimetallic
✍ Gregorio Sánchez; Francisca Momblona; Mateo Sánchez; José Pérez; Gregorio López; 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 333 KB

The compound cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] has been used as the between [(C 6 F 5 ) 2 Ni(&µ-X) 2 Ni-(C 6 F 5 ) 2 ] 2-and L. The treatment of cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] with [M(SAr) 2 (dppe)] leads to the starting material for the preparation of the bimetallic complexes ethane], and the Pt). Th