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Triphospholes as 2e and 4e donors: Synthesis and structural characterization of the 1,2,4-triphosphole complexes η1-trans-[PtCl2(PEt3)(P3C2Bu3.0.CO;2-H/asset/equation/tex2gif-stack-1.gif?v=1&t=h5m61cg7&s=fa3a6bf97af99c538117b88f2890f7c6562d34b9" class="inlineGraphic">CH(SiMe3)2] and η1-η1-trans-[PtCl2(PEt3)2}2(μ-P3C2Bu3.0.CO;2-H/asset/equation/tex2gif-stack-2.gif?v=1&t=h5m61cg7&s=7fb7c40667376fc773adea0fb5af23d3be67ce36" class="inlineGraphic">CH(SiMe3)2]

✍ Scribed by Vinicius Caliman; Peter B. Hitchcock; J. F. Nixon


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
376 KB
Volume
9
Category
Article
ISSN
1042-7163

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✦ Synopsis


The first examples of g 1 -complexes of 1,2,4-triphospholes are reported in which the ring acts as a 2e and a 4e donor.


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