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Laser-induced chemical kinetics: Absolute rate constants for the reactions Ċ2F2 + Br2 → C2F5Br + Ḃr and n-Ċ3F7 + Br2 → n-C3F7Br + Ḃr

✍ Scribed by M. J. Rossi; J. R. Barker; D. M. Golden

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
332 KB
Volume
14
Category
Article
ISSN
0538-8066

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✦ Synopsis

Absolute rate constants a t room temperature for the metathesis reaction C~FS + Br2 C2FSBr + Br and nd3F7 + Br2 CzFTBr + Br have been measured under V L P P conditions:

The radicals were generated through collisionless infrared-multiphoton decomposition of the corresponding iodides by irradiation from a high-power C02-TEA laser. The reaction of k 2 F ~ and &F7 with NO2 are briefly discussed in relation to the reaction of ks with NO2, which had been measured previously.

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