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The kinetics of the reactions of i-C3F7 radicals with BR2 and HBr

✍ Scribed by Ian Weeks; Eric Whittle

Publisher: John Wiley and Sons
Year: 1983
Tongue: English
Weight: 256 KB
Volume: 15
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550151208

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✦ Synopsis

The reactions (2)

(3) have been studied competitively in the vapor phase over the range of 52-204°C. The i-C3F7 radicals were generated by means of the reaction

It was found that log kz/k3 = (0.55 f 0.07) + (10,870 f 560)/0 where 0 = 2.303RT J/mol. Absolute Arrhenius parameters are derived for the reactions R + HBr + RH + Br where R = CF3, CzFs, and i-C3F7.

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