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The reaction of C2F5 radicals with H2S

✍ Scribed by J. E. Bassett; E. Whittle

Publisher: John Wiley and Sons
Year: 1972
Tongue: English
Weight: 410 KB
Volume: 4
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550040404

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✦ Synopsis

The reaction of CzF5 radicals with HzS

(2) C2F5 + HzS -+ CzF5H + HS kfi was studied over the range 1"-123"C using CZFS radicals generated by photolysis of perfluoropropionic anhydride.

The rate constant k~ for reaction (2) is given by where e = 2.303RT/cal mole-'. The relevance of this result to conflicting published data on the analogous reaction between CF, radicals and H2S is discussed. It is concluded that there is little difference in the Arrhenius parameters for reaction of CF3 and CzFs radicals with HZS.

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