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Reaction of CF3 radicals with C2H6

✍ Scribed by Haluk Arican; Neville L. Arthur

Publisher: John Wiley and Sons
Year: 1986
Tongue: English
Weight: 333 KB
Volume: 18
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550180403

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✦ Synopsis

The hydrogen transfer reaction between C2H6 and CFs radicals, generated by the photolysis of CF31, has been studied in the temperature range 298-617 K. The rate constant, based on the value of 1013 36 cm3 mo1-l s-' for the recombination of CFs radicals, is given by log kp = (11.90 2 0.09) -(33230 _t 740)/19.145 T

where k , is in cm3 mol-' s-1 and E is in J mol-'. These results are compared with those previously reported, and the following best value for k , is recommended: log k , = (11.94 * 0.07)

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