ChemInform Abstract: New or Improved Syntheses of the Polyfluoroalcohols HOC(cyclo-C6H11)2(CF3), HO(cyclo-C6H11)(CF3)2, and HOC(Ar)(CF3)2 (Ar = 4-C6H4(tBu), 2,4,6-C6H2(CF3)3, 4-Si(iPr)3-2,6-C6H2 (CF3)2, 3,5-C6H3(CH3)2), and 2-C6H4(C(OH)(CF3)2).
✍ Scribed by Thomas J. Barbarich; Benjamin G. Nolan; Shoichi Tsujioka; Susie M. Miller; Oren P. Anderson; Steven H. Strauss
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Trimethylamine-bis(trifluoromethyl) boranes R(CF 3 ) 2 B ´NMe 3 (R = cis/trans-CF 3 CF=CF (1/2), HCºC (3), H 2 C=CH (4), C 2 H 5 (5), C 6 H 5 CH 2 (6), C 6 F 5 (7), C 6 H 5 (8)) react with NEt 3 ´3 HF depending on the nature of R at 155±200 °C under replacement of the trimethylamine ligand to form
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