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Rates of reaction of atomic oxygen with C2H3F, C2H3Cl, C2H3Br, 1,1-C2H2F2, and 1,2-C2H2F2

✍ Scribed by Robert E. Huie; John T. Herron; Douglas D. Davis

Publisher: John Wiley and Sons
Year: 1972
Tongue: English
Weight: 298 KB
Volume: 4
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550040506

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✦ Synopsis

Rate constants for the reactions of atomic oxygen ( 0 3 P ) with C&3F, C&IaCl,C@3Br, 1, l-CzHzFz, and I ,2-C&IzFz have been measured at 307' K using a discharge-flow system coupled to a mass spectrometer. The rate constants for these reactions are (in units of 1011cm3mole-1s-1)2.63 &0.38,5.22 =tO0.24,4.90=t0.34,2.19&0.18,and2.70f0.34, respectively. For some of these reactions, the product carbonyl halides were identified. @ 1972 by John Wiley & Sons, Inc.

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