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Hydrothermal Synthesis, Structure, and Magnetism of [Co2(OH){1,2,3-(O2C)3C6H3}(H2O)]⋅H2O and [Co2(OH){1,2,3-(O2C)3C6H3}]: Magnetic Δ-Chains with Mixed Cobalt Geometries

✍ Scribed by Siegfried O. H. Gutschke; Daniel J. Price; Annie K. Powell; Paul T. Wood


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
154 KB
Volume
40
Category
Article
ISSN
0044-8249

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Kristallstruktur von Kaliumtriflat-Butyr
✍ Thorsten Gröb; Gert Seybert; Werner Massa; Andreas Greiner; Kurt Dehnicke 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 208 KB

Single Crystals of [K 3 (O 3 SCF 3 ) 3 (O 2 C 4 H 6 ) 2 ] (1) have been obtained as a by-product from the reaction of KNPPh 3 with Yb(O 3 SCF 3 ) 3 in THF with subsequent addition of butyrolactone. The structure of 1 consists of three symmetry-independent potassium ions which are linked by the oxyge