𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The mechanism of the thermal rearrangement of β-ketosilanes

✍ Scribed by Gerald L. Larson; Yvonne V. Fernandez


Book ID
108351572
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
265 KB
Volume
86
Category
Article
ISSN
0022-328X

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


The synthesis of olefins from β-ketosila
✍ Paul F. Hudrlik; David Peterson 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 155 KB

Sew Jerse:. C3903 Like acyloxysilanes, 1 p-ketosilanes can react with a nucleophile in two ways. We have found that the reaction of a S-ketosilane with alkoxide gives a product resulting from displacement at the silicon atom, while the reactions with Grignard reagents and with organolithium compoun

Magnesium iodide induced rearrangement o
✍ Michio Obayashi; Kiitiro Utimoto; Hitosi Nozaki 📂 Article 📅 1977 🏛 Elsevier Science 🌐 French ⚖ 164 KB

Recently ,!3-ketosilanes have attracted considerable attention as useful intermediate for stereoselective olefin synthesis. 1,2 This paper describes the rearrangement of a,@epoxysilanes induced by magnesium iodide affording a novel procedure for the synthesis of B-ketosilanes from readily accessible