The mechanism of the thermal rearrangement of β-ketosilanes
✍ Scribed by Gerald L. Larson; Yvonne V. Fernandez
- Book ID
- 108351572
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 265 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Sew Jerse:. C3903 Like acyloxysilanes, 1 p-ketosilanes can react with a nucleophile in two ways. We have found that the reaction of a S-ketosilane with alkoxide gives a product resulting from displacement at the silicon atom, while the reactions with Grignard reagents and with organolithium compoun
Recently ,!3-ketosilanes have attracted considerable attention as useful intermediate for stereoselective olefin synthesis. 1,2 This paper describes the rearrangement of a,@epoxysilanes induced by magnesium iodide affording a novel procedure for the synthesis of B-ketosilanes from readily accessible