𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The mechanism of solvolysis of β-ketosilanes

✍ Scribed by Mariella Fiorenza; Alessandro Mordini; Alfredo Ricci


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
349 KB
Volume
280
Category
Article
ISSN
0022-328X

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


The synthesis of olefins from β-ketosila
✍ Paul F. Hudrlik; David Peterson 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 155 KB

Sew Jerse:. C3903 Like acyloxysilanes, 1 p-ketosilanes can react with a nucleophile in two ways. We have found that the reaction of a S-ketosilane with alkoxide gives a product resulting from displacement at the silicon atom, while the reactions with Grignard reagents and with organolithium compoun

An efficient synthesis of β-ketosilanes
✍ Gerald L Larson; Ingrid Montes de López-Cepero; Luz E Torres 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 145 KB

The reaction of cc-silyl esters with an excess of a Grignard reagent leads to B-ketosilanes in good yield.

A novel synthesis of β-ketosilanes via o
✍ Narayan G Bhat; Chris Martinez; J De Los Santos 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 138 KB

A convenient, novel synthesis of b-ketosilanes based on (Z)-1-bromo-1-alkenylboronate esters is developed. a-Bromo-(Z)-1-alkenylboronate esters readily available using literature procedures smoothly undergo a reaction with trimethylsilylmethyllithium in tetrahydrofuran to provide the corresponding `