Sew Jerse:. C3903 Like acyloxysilanes, 1 p-ketosilanes can react with a nucleophile in two ways. We have found that the reaction of a S-ketosilane with alkoxide gives a product resulting from displacement at the silicon atom, while the reactions with Grignard reagents and with organolithium compoun
The mechanism of solvolysis of β-ketosilanes
✍ Scribed by Mariella Fiorenza; Alessandro Mordini; Alfredo Ricci
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 349 KB
- Volume
- 280
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The reaction of cc-silyl esters with an excess of a Grignard reagent leads to B-ketosilanes in good yield.
A convenient, novel synthesis of b-ketosilanes based on (Z)-1-bromo-1-alkenylboronate esters is developed. a-Bromo-(Z)-1-alkenylboronate esters readily available using literature procedures smoothly undergo a reaction with trimethylsilylmethyllithium in tetrahydrofuran to provide the corresponding `
Product selectivities from solvolysis of l-adamantyl bromide in several binary protic solvents are revealing about the relative importance of solvent acidity and bulk (