Sew Jerse:. C3903 Like acyloxysilanes, 1 p-ketosilanes can react with a nucleophile in two ways. We have found that the reaction of a S-ketosilane with alkoxide gives a product resulting from displacement at the silicon atom, while the reactions with Grignard reagents and with organolithium compoun
✦ LIBER ✦
An efficient synthesis of β-ketosilanes
✍ Scribed by Gerald L Larson; Ingrid Montes de López-Cepero; Luz E Torres
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 145 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The reaction of cc-silyl esters with an excess of a Grignard reagent leads to B-ketosilanes in good yield.
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