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The synthesis of olefins from β-ketosilanes

✍ Scribed by Paul F. Hudrlik; David Peterson

Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
155 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis

Sew Jerse:. C3903 Like acyloxysilanes, 1 p-ketosilanes can react with a nucleophile in two ways.

We have found that the reaction of a S-ketosilane with alkoxide gives a product resulting from displacement at the silicon atom, while the reactions with Grignard reagents and with organolithium compounds give only products re-2 sulting from addition to the carbonyl group.

Since the p-hydroxyalkylsilanes B formed in the latter reactions can be converted into olefins, the process serves as a potential synthetic route to these compounds.

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