Electroreductive synthesis of olefins from β-hydroxysulfides
✍ Scribed by Tatsuya Shono; Yoshihiro Matsumura; Shigenori Kashimura; Hirofumi Kyutoku
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 438 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Reductive elimination of groups including sulfur from organosulfur compounds has been extensively studied' from the viewpoint of organic synthesis.
📜 SIMILAR VOLUMES
Sew Jerse:. C3903 Like acyloxysilanes, 1 p-ketosilanes can react with a nucleophile in two ways. We have found that the reaction of a S-ketosilane with alkoxide gives a product resulting from displacement at the silicon atom, while the reactions with Grignard reagents and with organolithium compoun
A simple, general, and highly regioselective procedure has been developed for the one-pot synthesis of b-hydroxysulfides in good yields from various styrenes and disulfides by cleavage of the S-S bond with a Zn/AlCl 3 system in aqueous acetonitrile at 80 °C and in the presence of oxygen.