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The Thio-Claisen Rearrangement. The Mechanism of Thermal Rearrangement of Allyl Aryl Sulfides

โœ Scribed by Kwart, Harold; Evans, E. Robert

Book ID
120364960
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
1011 KB
Volume
31
Category
Article
ISSN
0022-3263

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Earlier, we reported that the thio-Cloisen reorrongement of ally1 4quinolyl sulfides (I) to 2,3-dihydrothieno[3.2-clquinolines (III) proceeded through the prototropic cyclizotion of the initially formed 3-allyl-4(1 H)-quinolinethiones (II), on the basis of the quantitative transformation of II into