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The mechanism of the β-ketosilane to siloxyalkene thermal rearrangement

✍ Scribed by A.G. Brook; D.M. MacRae; Alan R. Bassindale

Book ID
108351571
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
577 KB
Volume
86
Category
Article
ISSN
0022-328X

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Magnesium iodide induced rearrangement o
Magnesium iodide induced rearrangement of α,β-epoxysilanes to β-ketosilanes as applied to the stereoselective synthesis of tetrahomoterpenoid of codling moth
✍ Michio Obayashi; Kiitiro Utimoto; Hitosi Nozaki 📂 Article 📅 1977 🏛 Elsevier Science 🌐 French ⚖ 164 KB

Recently ,!3-ketosilanes have attracted considerable attention as useful intermediate for stereoselective olefin synthesis. 1,2 This paper describes the rearrangement of a,@epoxysilanes induced by magnesium iodide affording a novel procedure for the synthesis of B-ketosilanes from readily accessible