✦ LIBER ✦
Magnesium iodide induced rearrangement of α,β-epoxysilanes to β-ketosilanes as applied to the stereoselective synthesis of tetrahomoterpenoid of codling moth
✍ Scribed by Michio Obayashi; Kiitiro Utimoto; Hitosi Nozaki
- Book ID
- 104235907
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 164 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Recently ,!3-ketosilanes have attracted considerable attention as useful intermediate for stereoselective olefin synthesis. 1,2 This paper describes the rearrangement of a,@epoxysilanes induced by magnesium iodide affording a novel procedure for the synthesis of B-ketosilanes from readily accessible vinylsilanes. 3 An application of this procedure to the stereoselective olefin