Synthesis of Tetrakis(dimethylamino)ethylene
β Scribed by Weingarten, Harold; White, William A.
- Book ID
- 120978773
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 248 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0022-3263
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Tetrakis(dimethylamino)ethylene (TDAE) was found to be an effective reductant of chlorodifluoromethylated ketones 1-3. The generated ~,~-difluoroacetyl anion was trapped with several aldehydes 4-7, under mild conditions, to give the corresponding 2,2-difiuoro-3-hydroxy ketone derivatives 8-13, in mo