Synthesis of 1,4-Diketones: Reaction of α-Bromo Ketones with Tetrakis(dimethylamino)ethylene (TDAE).
✍ Scribed by Yutaka Nishiyama; Akihiro Kobayashi
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 26 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
📜 SIMILAR VOLUMES
Tetrakis(dimethylamino)ethylene (TDAE) as a Useful Reductant of Some Chlorodifluoromethylated Ketones. A New Approach for the Synthesis of α,α-Difluoroketone Derivatives. -Reduction of chlorodifluoromethylated ketones with TDAE as an effective reductant generates α,α-difluoroacetyl anions, which ar
## Abstract A series of 2,2‐disubstituted 5,6‐diphenyl‐4H‐1,3‐oxathiin‐4‐ones was synthesized by cycloaddition of thiones with benzoylphenylketene, which was generated by the thermal Wolff rearrangement of 2‐diazo‐1,3‐diphenyl‐1,3‐propanedione. © 2001 John Wiley & Sons, Inc. Heteroatom Chem 12:630–