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ChemInform Abstract: Tetrakis(dimethylamino)ethylene as a Useful Reductant of Some Bromodifluoromethyl Heterocycles. Application to the Synthesis of New gem-Difluorinated Heteroarylated Compounds.

โœ Scribed by C. BURKHOLDER; W. R. JUN DOLBIER; M. MEDEBIELLE


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Tetrakis(dimethylam
โœ C. BURKHOLDER; W. R. JUN. DOLBIER; M. MEDEBIELLE; A. NDEDI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 2 views

Tetrakis(dimethylamino)ethylene (TDAE) as a Useful Reductant of Some Chlorodifluoromethylated Ketones. A New Approach for the Synthesis of ฮฑ,ฮฑ-Difluoroketone Derivatives. -Reduction of chlorodifluoromethylated ketones with TDAE as an effective reductant generates ฮฑ,ฮฑ-difluoroacetyl anions, which ar