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A New Synthesis of Tetrakis(dimethylamino)ethylene

✍ Scribed by Prof. H. Bredereck; Dr. F. Effenberger; H. J. Bredereck

Publisher
John Wiley and Sons
Year
1966
Tongue
English
Weight
123 KB
Volume
5
Category
Article
ISSN
0044-8249

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Tetrakis(dimethylamino)ethylene (TDAE) as a Useful Reductant of Some Chlorodifluoromethylated Ketones. A New Approach for the Synthesis of Ξ±,Ξ±-Difluoroketone Derivatives. -Reduction of chlorodifluoromethylated ketones with TDAE as an effective reductant generates Ξ±,Ξ±-difluoroacetyl anions, which ar