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Synthesis of Optically Active α-Aminomethylketones. 1 Amino Acids. XXIV.

✍ Scribed by BALENOVIC, K.; THALLER, V.


Book ID
127279452
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
189 KB
Volume
21
Category
Article
ISSN
0022-3263

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Practical synthesis of optically active
✍ Joëlle Viret; Jacqueline Gabard; André Collet 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 290 KB

Simple amino acids (1) can be converted in fair to good yield into hydrazino acids (3) of like configuration by using KOCI instead of NaOCl to promote the Shestakov rearrangement of the intermediate hydantoic acids (2). It was shown fifteen years ago by Karady et al.,' and later by Custafsson,' that