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Synthesis of 13C- and 14C-Labeled methanesulfinic and methanesulfonic acids

✍ Scribed by V. J. Feil; J. K. Huwe; D. M. Dulik; C. Fenselaum

Publisher
John Wiley and Sons
Year
1988
Tongue
French
Weight
332 KB
Volume
25
Category
Article
ISSN
0022-2135

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✦ Synopsis

The enzyme catalyzed displacement o f the methyl s u l f o n y l group from pentachlorophenyl methyl sulfone, the pchloroperoxybenzoic a c i d oxidation of methyl mercaptan and the reaction o f m e t h y l l i t h i u n with sulfur dioxide are methods described f o r the synthesis o f i s o t o p i c a l l y labeled methanesulfinic acid. The f i r s t two methods can be c a r r i e d out on a milligram scale and are suitable for high s p e c i f i c a c t i v i t y preparations while the l a t t e r method i s suitable for preparations on a gram scale. i s o t o p i c a l l y labeled methanesulfonic acid.

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