An amorphous Ta-Zr binary alloy diffusion barrier was studied in the Cu metallization. A Cu/Ta 50 Zr 50 /SiO 2 /Si stack with 50 nm thick amorphous film was prepared by co-sputtering can effectively suppress the penetration of Cu atoms into substrate upon annealing up to 650 °C. Examining the therma
Study of nanocrystalline Ta(N,O) diffusion barriers for use in Cu metallization
✍ Scribed by Momtchil Stavrev; Dirk Fischer; Andrea Preuß; Christian Wenzel; Norbert Mattern
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 367 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0167-9317
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✦ Synopsis
In this study, the film properties and the barrier behaviour of 50 nm thin reactively sputtered Ta(N,O) diffusion barriers between Cu and Si were investigated. Auger electron microscopy, glancing-angle x-ray diffractometry and atomic force microscopy revealed that the Ta(N,O) films exhibit quasi-amorphous/nanocrystalline properties. Using sheet resistance measurements, scanning electron microscopy, Auger electron spectroscopy depth profiling and conventional x-ray diffractometry the 50 nm thin Ta(N,O) films were found to be effective diffusion barriers between Cu overlayers and Si substrates even after 1 h annealing at 600°C.
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In this paper the investigation of r.f.-sputter-deposited Ta, Ta-N and Ta-N-O thin Ðlms is presented. Using atomic force microscopy in combination with sheet resistance measurements, Auger electron spectroscopy and x-ray diffraction, the thin Ðlm properties and microstructure are examined. Two cryst