Reactions of hydrocarbon ions with hydrogen and methane at 300 K
β Scribed by N.G. Adams; D. Smith
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 533 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The rate coefficients and ionised product distributions have been determined for reactions of the ions CH: and CzHz with Hz and CH4. for R = 0 to 4, in a SIFT apparatus at 300 K. The reactions are fast and mukiple products result from the CH4 reactions.
π SIMILAR VOLUMES
The rate coeffkients and product Ion distributions have been obtained for the reactions of the CHZ ions (n = 0 to 4) with COS, H2S, HaCO, CHsOH and CHBNHz in a SIFT at 300 K. The reactions are generally fast binary with mulriple products except for CHf for which fast ternary association channels are
Ihe semi-empirical version of Marcus' theory of electron transfer is slightly modified in order to account for the perturbing influence of the Na+ ion in the photo-ionization of associates of aromhtichydrocarbon negative ions and Naf ions. As an example j qualitatite interpretation is given of the p
## Thermal rate coeffrclents and product dlstributlons for the reactrons of ground-and met&able-state Cl\* tons with several neutral molecules have been studled usmg a selected ran flow tube (SIFT) apparatus. In most cases, the mqor rcactlon channel 1s charge transfer In general, the metastable I