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Reactions of HnCO+ ions with molecules at 300 K

✍ Scribed by N.G. Adams; D. Smith; D. Grief

Publisher: Elsevier Science
Year: 1978
Weight: 830 KB
Volume: 26
Category: Article
ISSN: 0020-7381
DOI: 10.1016/0020-7381(78)80059-x

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The rate coeffkients and product Ion distributions have been obtained for the reactions of the CHZ ions (n = 0 to 4) with COS, H2S, HaCO, CHsOH and CHBNHz in a SIFT at 300 K. The reactions are generally fast binary with mulriple products except for CHf for which fast ternary association channels are

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## Thermal rate coeffrclents and product dlstributlons for the reactrons of ground-and met&able-state Cl\* tons with several neutral molecules have been studled usmg a selected ran flow tube (SIFT) apparatus. In most cases, the mqor rcactlon channel 1s charge transfer In general, the metastable I

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Thermal reaction of HNCO with NO2 at mod

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## Abstract The thermal reaction of HNCO with NO~2~ has been studied in the temperature range of 623 to 773 K by FTIR spectrometry. Major products measured are CO~2~ and NO with a small amount of N~2~O. Kinetic modeling of the time resolved concentration profiles of the reactants and products, aide