Reaction of the ground and metastable excited Cl+ ions with several neutral molecules at 300 K
β Scribed by Asit B. Rakshit
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 330 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Thermal rate coeffrclents and product dlstributlons
for the reactrons of ground-and met&able-state Cl* tons with several neutral molecules have been studled usmg a selected ran flow tube (SIFT) apparatus.
In most cases, the mqor rcactlon channel 1s charge transfer In general, the metastable Ion reaction rates are fast, near gas-kmetic
1. introduction
Recently, It has been possrble to drstingtush reac-
π SIMILAR VOLUMES
Metastable excited CI' was recently reported by Rakshit in a study using the Aberystwyth SIFT apparatus. We conclude that this report refers to a mixture of Cl+ and HCl+, and that the results are hence erroneous. Our recent work using the same apparatus gives no evidence for excited Cl+.
The rdt, cocii~c~cnts and product eon dlsrrlbutlons for rhc reactions ot OH\* and tlzO+ u ith N2\_ 02 h'0 X20 Xc, CO, CO? H2S Jnd 112 hd\c been dctermlned it 194 + 2 K usmg a selcctcd ton ilo\. rubc (SIFT) dppclrnrus These reactIons urre generally found to proLccd b\~ athcr proton or charge trsnsfcr