Hydrogen containing tritium was atomized at a hot tungsten filament, and the atoms were reacted with carbon (graphite, lamp black and diamond) at 77Β°K. At pressures low enough to allow a collision-free path for the hydrogen atoms between the filament and the surface of the carbon, CH,, CsH,, CsHs, i
Reaction of hydrogen atoms with solid unsaturated hydrocarbons at 77 K
β Scribed by Kenzo Hiraoka; Kazumasa Matsunaga; Takashi Shoda; Hajime Takimoto
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 460 KB
- Volume
- 197
- Category
- Article
- ISSN
- 0009-2614
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The rate coefficients and ionised product distributions have been determined for reactions of the ions CH: and CzHz with Hz and CH4. for R = 0 to 4, in a SIFT apparatus at 300 K. The reactions are fast and mukiple products result from the CH4 reactions.
## Abstract Rate coefficients for the reaction of Cl atoms with cycloalkenes have been determined using the relative rate method, at 298 K and atmospheric pressure of N~2~. Reference molecule was __n__βhexane, and the concentrations of the organics were followed by gas chromatographic analysis. Cl