This communication reports a simple, rapid and convenient means of converting sulfonyl chlorides I to thiolsulfonate esters II using a 1:l mixture of iron pentacarbonyl and boron trifluoride ether-ate in N,N-dimethylacetamide (DMAC) or tetramethylurea (TMU). A typical procedure follows. BFx.(C7H5)7
โฆ LIBER โฆ
Reaction of Iron Pentacarbonyl with gem-Dihalides
โ Scribed by Coffey, C. Eugene
- Book ID
- 126917454
- Publisher
- American Chemical Society
- Year
- 1961
- Tongue
- English
- Weight
- 578 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0002-7863
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In 1959, Hieber and Lipp' reported briefly the deoxygenatlon of pyridine N-oxide with iron pentacarbonyl. In view of the highly polar N-C bond of Nnitrosamines (which can formally be viewed as N-nltrene N-oxides), the action of iron pentacarbonyl of N-nltrosamlnes was considered as a possible route