✦ LIBER ✦

The reaction of N,N-dibenzylnitrosamine with iron pentacarbonyl

✍ Scribed by A. Tanaka; J.-P. Anselme

Publisher: Elsevier Science
Year: 1971
Tongue: French
Weight: 185 KB
Volume: 12
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)97232-6

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✦ Synopsis

In 1959, Hieber and Lipp' reported briefly the deoxygenatlon of pyridine N-oxide with iron pentacarbonyl. In view of the highly polar N-C bond of Nnitrosamines (which can formally be viewed as N-nltrene N-oxides), the action of iron pentacarbonyl of N-nltrosamlnes was considered as a possible route to N-nltrenes.

2 When dibenzglnltrosamlne was refluxed for 20 hrs. In purified

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