The reaction of N,N-dimethyl- and N,N-diethylaniline with silicon tetrabromide
✍ Scribed by H. Breederveld
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 139 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0165-0513
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✦ Synopsis
Abstract
N‐methylanilino‐tribromosilane, N‐ethylanilino‐tribromosilane, and di(N‐ethylanilino)‐dibromosilane have been prepared from the corresponding N,N‐dialkylaniline and silicon tetrabromide at about 180°.
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The reaction of arylaldehydes 1 and N,N-dimethylacrylamide in the presence of tributylphosphine afforded N,Ndimethyl-3-aroylpropionamides 2 in moderate yields. The reaction might involve the formation of a-oxo ylide A.
SUM!.4ARY: The action 06 N,N-dibenzy1tibamoyL ckeohide (21 on -the bodium da.& 06 N-niattobo-hy&oxy&minti (11 in dhy actiome at he&&ix .&&4 ti pmduc& whobe ,(otmati\_on may be trationaL&d in &amb 06 canbamoylatin aR e&heh oxygen 06 the bididen&zte N-tiobohy&oxy,kmi.mb.