The reaction of disubstituted carbamoyl chlorides and sulfamoyl chlorides with sodium nitrite in acetonitrile has been shown to afford N-nitrosamines in excellent yields. In 1959, Norris had described the reaction of dialkylcarbamoyl chlorides with silver nitrate: mixtures of dialkylnitramines and
The reaction of n,n-dibenzylcarbamoyl chloride with n-nitrosohydroxylamine
β Scribed by Masayuki Nakajima; Jean-Pierre Anselme
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 119 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
SUM!.4ARY: The action 06 N,N-dibenzy1tibamoyL ckeohide (21 on -the bodium da.& 06 N-niattobo-hy&oxy&minti (11 in dhy actiome at he&&ix .&&4 ti pmduc& whobe ,(otmati_on may be trationaL&d in &amb 06 canbamoylatin aR e&heh oxygen 06 the bididen&zte N-tiobohy&oxy,kmi.mb.
π SIMILAR VOLUMES
The major products of the hydrolysis of N,O-dibenzyl-N-nitrosohydroxylamines (3) are the denitrosated parent hydroxylamines (6); under mom forcing conditions, products of the further hydrolysis of 6 are obtained. Acetolysis in acetic acid gives the benzyl acetates derived from both N-and 0-substitue