The Reaction of Camphene with N-Carbonylsulfamyl Chloride
β Scribed by Dr. habil. R. Graf; Dr. H. Biener
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- English
- Weight
- 132 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
Reaction of commercially available trialkyl phosphites with N-phthalylamino acids gave mixtures of seven products, whereas the same reaction carried out with pure triethyl phosphite yielded only the desired 2-(N-phthalylamino)-1-oxoalkanephosphonates. These compounds underwent rearrangement to the s
of 12 e 1 kcal mole-1 for reaction (1); this value is somewhat smaller than that reported [I], wilhout error limits, for 100 atrn. From the pressure dependence at 23OC, in conjunction with Eq. (2), a volume change, AV, associated with the reaction of 64 f 3 ml/mole is obtained. Both A H and A V decr