𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reaction of iron pentacarbonyl with sulfonyl chlorides

✍ Scribed by Howard Alper

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
166 KB
Volume
10
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

This communication reports a simple, rapid and convenient means of converting sulfonyl chlorides I to thiolsulfonate esters II using a 1:l mixture of iron pentacarbonyl and boron trifluoride ether-ate in N,N-dimethylacetamide (DMAC) or tetramethylurea (TMU). A typical procedure follows.

BFx.(C7H5)70

πŸ“œ SIMILAR VOLUMES

The reaction of N,N-dibenzylnitrosamine
The reaction of N,N-dibenzylnitrosamine with iron pentacarbonyl
✍ A. Tanaka; J.-P. Anselme πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 185 KB

In 1959, Hieber and Lipp' reported briefly the deoxygenatlon of pyridine N-oxide with iron pentacarbonyl. In view of the highly polar N-C bond of Nnitrosamines (which can formally be viewed as N-nltrene N-oxides), the action of iron pentacarbonyl of N-nltrosamlnes was considered as a possible route