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Iron(III) Chloride-Catalyzed Direct Sulfonylation of Alcohols with Sodium Arenesulfinates

✍ Scribed by M. Amarnath Reddy; P. Surendra Reddy; B. Sreedhar


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
228 KB
Volume
352
Category
Article
ISSN
1615-4150

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✍ Yu Yuan; Zhuangzhi Shi; Xuan Feng; Xiangnong Liu πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 142 KB

## Abstract The direct substitution of alcohols and β‐dicarbonyl compounds was catalyzed with FeCl~3~ under solvent‐free conditions. The catalyst loading could be decreased to 0.01 mol% at high activities. It was shown that the reaction proceeded in two steps via the etherification of the alcohols.