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Efficient Iron-Catalyzed Direct β-Alkylation of Secondary Alcohols with Primary Alcohols

✍ Scribed by Jian Yang; Xin Liu; Da-Li Meng; Hong-Yan Chen; Zhi-Hui Zong; Ting-Ting Feng; Kai Sun

Publisher: John Wiley and Sons
Year: 2012
Tongue: English
Weight: 228 KB
Volume: 354
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.201000907

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## Abstract “__Deficient” but “efficient__”, the first example of a catalytic Friedel–Crafts alkylation of arenes, carrying electron‐withdrawing groups, with alcohols is reported. The optimized iron(III) chloride (97%) catalyzed allylation, benzylation and propargylation procedures open an access t