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Reaction of iron pentacarbonyl with ethyl dichloroacetoacetate and dichloroacetylacetone

โœ Scribed by F. K. Velichko; R. A. Amriev; Z. A. Abdulkina; S. I. Kuznetsov


Book ID
112443710
Publisher
Springer
Year
1985
Tongue
English
Weight
173 KB
Volume
34
Category
Article
ISSN
1573-9171

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Reaction of iron pentacarbonyl with sulf
โœ Howard Alper ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 166 KB

This communication reports a simple, rapid and convenient means of converting sulfonyl chlorides I to thiolsulfonate esters II using a 1:l mixture of iron pentacarbonyl and boron trifluoride ether-ate in N,N-dimethylacetamide (DMAC) or tetramethylurea (TMU). A typical procedure follows. BFx.(C7H5)7